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THQphos in Ir-catalyzed Asymmetric Allylic Substitution Reactions

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The 1,2,3,4-tetrahydroquinoline phosphoramidites (THQphos) have been found to be efficient ligands for iridium-catalyzed asymmetric allylic substitution reactions. In this short review article, an overall introduction on the development of THQphos, involving their original design, preparation, mechanistic studies, applications and features will be described.
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Keywords: ALLYLIC SUBSTITUTION; ASYMMETRIC CATALYSIS; IRIDIUM; THQPHOS

Document Type: Research Article

Affiliations: 1: State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China 2: State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), 300072, China;, Email: [email protected]

Publication date: September 1, 2018

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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