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Open Access Ynol Ethers: Synthesis and Reactivity

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Ynol ethers are highly valuable substrates offering a wide range of reactivity. These highly electron-rich heterosubstitued alkynes can be of great synthetic potential. In this mini-review, the different methods for the synthesis of ynol ethers are first presented, divided in three main approaches involving a β-elimination, a carbene rearrangement and a direct oxidation of an alkyne. Their reactivity is then summarized underlying their synthetic utility. This non-exhaustive review aims at presenting the intrinsic reactivity of these compounds, still underexploited in synthesis.

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Keywords: ALKYNES; ENOL ETHERS; KETENES; SYNTHESIS; YNOL ETHERS

Document Type: Research Article

Affiliations: 1: Université Grenoble Alpes, Département de Chimie Moléculaire (SERCO), UMR-5250 CNRS, IMCG FR-2607, 38041 Grenoble, France 2: Université Grenoble Alpes, Département de Chimie Moléculaire (SERCO), UMR-5250 CNRS, IMCG FR-2607, 38041 Grenoble, France;, Email: [email protected]

Publication date: February 1, 2016

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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