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Open Access Free-radical Carbo-functionalization of Olefins Using Sulfonyl Derivatives

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This review provides an overview of the recent progress made in the area of free-radical additions across the π-system of olefins, with a focus on the role of sulfonyl derivatives as one of the reaction partners in multicomponent processes. The mechanism and utility in organic synthesis of carbo-alkenylation, alkynylation, oximation and azidation of olefins are thus discussed and illustrated with some applications in total synthesis of natural products.

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Keywords: ALLYLATION; AZIDATION; CARBONYLATION; OXIMATION; RADICAL ADDITION; SULFONES; β-FRAGMENTATION

Document Type: Research Article

Publication date: February 1, 2016

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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