Skip to main content
padlock icon - secure page this page is secure

Open Access Polymer-containing Organo-Polyoxometalate: Towards New Catalytic Object

Download Article:
 Download
(PDF 405.7 kb)
 
Polyoxometalates (POMs) are early transition metal oxide clusters, which form a diverse family of compounds with highly tunable shapes, sizes, charges, etc. Generating hybrid structures is an attractive path to increase the structural diversity of POMs. The present article is a personal account that retraces how we inserted polyoxometallic platforms onto polymeric chains. We focused on two main families of functionalized organo-POMs: the organotin-substituted Dawson polyoxotunstates α1 and α2-[P2W17O61(SnR)]7– and the Dawson vanadotungstates [P2V3W15O59{(OCH2)2-C(Et)NHC(=O)R}]5–. Herein we discuss how the connection of POMs to polymers affects the self-assembly of the polymers and the catalytic properties of the polyoxometalates.

8 References.

No Supplementary Data.
No Article Media
No Metrics

Keywords: CATALYSIS; HYBRID MATERIALS; ORGANIC–INORGANIC HYBRIDS; POLYMERS; POLYOXOMETALATES

Document Type: Research Article

Affiliations: Laboratoire LHCEP (UMR 5278) Université Claude Bernard Lyon 1, Villeurbanne, France;, Email: [email protected]

Publication date: February 1, 2016

More about this publication?
  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Information for Advertisers
  • Ingenta Connect is not responsible for the content or availability of external websites
  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more