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Open Access Synthesis and Reactivity of Zn–Biphenyl Metal–Organic Frameworks, Introducing a Diphenylphosphino Functional Group

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Structural features, synthesis, and reactivity of Zn–biphenyl metal–organic frameworks with MOF-5 topology are presented to show the chemical flexibility of such materials and to demonstrate the challenges that can be encountered and solved to avoid interpenetration. We introduce the synthesis of a Zn–biphenyl MOF with diphenylphosphino functionalization and illustrate its structural and chemical properties.
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Keywords: METAL–ORGANIC FRAMEWORKS; MOF-5

Document Type: Research Article

Affiliations: 1: Laboratory of Catalysis and Sustainable Chemistry Paul Scherrer Institute CH-5232 Villigen PSI, Switzerland. [email protected] 2: Laboratory of Catalysis and Sustainable Chemistry Paul Scherrer Institute CH-5232 Villigen PSI, Switzerland; Laboratory for Chemical and Bioengineering ETH Zurich Wolfgang Pauli Strasse, 10 CH-8093 Zürich, Switzerland. [email protected]

Publication date: May 1, 2013

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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