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Open Access R-isophthalic Acid-based Coordination Polymers (R = Hydrogen or Bromine)

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Three new R-isophthalic acid-based (R = H or Br) coordination polymers have been designed and synthesized. By changing the N-containing ligand in the system, we are able to tune the dimensionality of coordination polymers from one-dimension (1D) to two-dimensions (2D) with the same basic building unit. Also, different metal ions can be incorporated into the same structures. Compound 1 [Cu(bipa)(py)2]·0.5(H2O) (H2bipa = 5-bromoisophthalic acid; py = pyridine) and compound 2 [Co(bipa)(py)2] are 1D chain structures. Compound 3 [Cu8(ipa)8(bpe)8]·2(bpe)·4(H2O) (bpe=1,2-bis(4-pyridyl)ethane) is a 2D layered structure.
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Keywords: 1D AND 2D POLYMERS; COORDINATION POLYMERS; ISOPHTHALIC ACID; N LIGANDS; SOLVOTHERMAL REACTION

Document Type: Research Article

Affiliations: 1: Department of Chemistry and Chemical Biology Rutgers University 610 Taylor Road, Piscataway, NJ, 08854, USA 2: Department of Chemistry and Chemical Biology Rutgers University 610 Taylor Road, Piscataway, NJ, 08854, USA. [email protected]

Publication date: May 1, 2013

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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