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Open Access Coordination Polymers Constructed from Oligonuclear Nodes

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The node-and-spacer approach is widely employed in crystal engineering to construct coordination polymers. It consists of self-assembly processes involving mononuclear cationic species and exo-dentate ligands. We enlarged this strategy using preformed homo- and heterometallic complexes as nodes. The presence of two or more metal ions within a node leads to novel network topologies, as well as to new properties, arising from the intra- and internode interactions. This paper reviews some representative examples of coordination polymers obtained in our laboratory and constructed from: i) binuclear alkoxo-bridged complexes; ii) heterometallic 3d-3d' and 3d-4f complexes.
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Keywords: COORDINATION POLYMERS; NODE-AND-SPACER

Document Type: Research Article

Affiliations: Inorganic Chemistry Laboratory, Faculty of Chemistry University of Bucharest Str. Dumbrava Rosie nr. 23 020464-Bucharest, Romania. [email protected]

Publication date: May 1, 2013

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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