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Open Access α-Trimethylsilylmethylamine Radical Cation in the Synthesis of Cyclic Amines and Beyond

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The evolution of chemistry associated with the photoinduced electron transfer (PET)-generated α-trimethylsilylmethylamine radical cation cyclization to a tethered olefin to synthesize cyclic amine structural frame works is presented in chronological order. The importance of this interesting chemistry is demonstrated by the synthesis of several novel glycosidase inhibitors.
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Keywords: 1-N-IMINOSUGARS; GLYCOSIDASE INHIBITORS; PHOTOINDUCED ELECTRON TRANSFER (PET); α-AMINE RADICAL; α-TRIMETHYLSILYL METHYLAMINE RADICAL CATION

Document Type: Research Article

Affiliations: 1: Division of Organic Chemistry National Chemical Laboratory Pashan Road, Pune 411008, India, Molecular Synthesis Laboratory, CBMR Sanjay Gandhi Post-graduate Institute of Medical Sciences, Campus Raebareli Road, Lucknow 226014, India. [email protected] 2: Division of Organic Chemistry National Chemical Laboratory Pashan Road, Pune 411008, India

Publication date: February 1, 2013

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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