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Open Access Teaching Enantioselectivity to C–H Bond Functionalizations: Initial Steps of a Rather Long Shot

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The direct functionalization of non-activated C–H bonds, especially in an enantioselective manner, requires metal catalysts equipped with ligands with specifically designed properties. Examples for asymmetric C(sp2)–H and C(sp3)–H functionalizations using palladium- and rhodium catalysts are shown. This work was rewarded by the 2012 Werner Prize of the Swiss Chemical Society.
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Keywords: ASYMMETRIC CATALYSIS; C–H ACTIVATION; LIGANDS; PALLADIUM; RHODIUM

Document Type: Research Article

Affiliations: Ecole Polytechnique Fédérale de Lausanne, EPFL SB ISIC LCSA, BCH 4305, CH-1015 Lausanne, Switzerland. [email protected]

Publication date: November 1, 2012

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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