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Open Access Enzyme-triggered Radical Reactions: Another Approach For Tin-free Radical Chemistry

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The system laccase/mediator/dioxygen is able to trigger radical reactions with radical precursors which are not natural substrates of this enzyme. The radical generation has been accomplished by single electron transfer oxidation of a 1,3-dicarbonyl precursor. The process is exemplified with a radical cascade.

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Keywords: 1,3-DICARBONYL COMPOUNDS; LACCASE; OXIDOREDUCTASE; RADICAL MEDIATOR; RADICAL REACTION

Document Type: Research Article

Affiliations: 1: Aix-Marseille Univ, Institut de Chimie Radicalaire UMR 7273, Equipe Chimie Moléculaire Organique, 13397 Cedex 20, Marseille, France 2: Aix-Marseille Univ, Institut Méditerranéen de Biodiversité et d'Ecologie UMR CNRS IRD 7263, Equipe Vulnérabilité des Systèmes Microbiens Faculté des Sciences et Techniques de St Jérôme, 13397, Marseille, Cedex 20, France 3: Aix-Marseille Univ, ISM2 UMR 7313, Equipe Chirosciences, 13397 Cedex 20, Marseille, France

Publication date: June 1, 2012

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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