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Open Access Some Aspects of the Radical Chemistry of Xanthates

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Xanthates and related thiocarbonylthio derivatives have proved to be exceedingly useful substrates for both inter- and intra- molecular radical additions. The intermolecular addition to unactivated alkenes, in particular, provides tremendous opportunities for synthesis: various functional groups can be brought together under mild, neutral conditions. Since the adduct is also a xanthate, iteration allows the formation of block polymers through a controlled radical polymerisation (the RAFT/MADIX technology). Also of some importance is the access to highly substituted aromatic and heteroaromatic derivatives.

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Keywords: BLOCK COPOLYMERS; CARBON-CARBON FORMATION; HETEROCYCLES; RADICAL ADDITIONS; XANTHATES

Document Type: Research Article

Affiliations: Ecole Polytechnique, Laboratoire de Synthèse Organique, UMR 7652, 91128 Palaiseau, France

Publication date: June 1, 2012

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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