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Open Access NHC-Boranes: Air- and Water-tolerant Co-initiators for Type II Photopolymerizations

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N-Hetereocyclic carbene (NHC) complexes of boranes are stable compounds that can be used as co-initiators for the type II photopolymerization of acrylates. The present account summarizes this new development for polymerization and boron chemistry. In particular, NHC-boranes are air- and water-tolerant, which enhances the practicality of the photopolymerizations.

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Keywords: BORON; CARBENES; FREE RADICALS; NHC-BORANES; PHOTOPOLYMERIZATION

Document Type: Research Article

Affiliations: 1: ICSN CNRS, Av. de la Terrasse, F-91198 Gif s/Yvette Cedex, France 2: University of Pittsburgh, Department of Chemistry, Pittsburgh, PA 15260, USA 3: IS2M - LRC CNRS 7228, ENSCMu-UHA, 15 rue Jean Starcky, F-68057 Mulhouse Cedex, France

Publication date: June 1, 2012

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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