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Open Access Rhenium Complexes as Highly Active Catalysts for the Hydrosilylation of Carbonyl Compounds

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[Re(P i Pr3)2(NO)2]+[B(C6F5)4] (1) and the new NO-functionalized compounds [Re(H)(P i Pr3)2(NO)(NOB(C6F5)3)] (2) and [Re(H)(NO)(NOEt)(P i Pr3)2]+[B(C6F5)4] (3) were prepared and found to be excellent catalysts for hydrosilylation of ketones. For 2 and 3 the hydrosilylation procedures are selective, mild, and efficient, and offer very practical methodologies to prepare the respective silyloxy compounds in quantitative yields. In exemplary experiments catalyst 2 could even be recovered.

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Keywords: CARBONYL COMPOUNDS; CATALYTIC HYDROSILYLATION; COORDINATION CHEMISTRY; DINITROSYL RHENIUM COMPLEXES; NO-FUNCTIONALIZED COMPOUNDS

Document Type: Research Article

Publication date: March 1, 2005

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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