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Open Access Chemical Pressure

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The physical and photophysical properties of three classic transition metal complexes, namely [Fe(bpy)3]2+, [Ru(bpy)3]2+, and [Co(bpy)3]2+, can be tuned by doping them into a variety of inert crystalline host lattices. The underlying guest-host interactions are discussed in terms of a chemical pressure.

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Keywords: CHEMICAL PRESSURE; GUEST-HOST INTERACTION; INTERSYSTEM CROSSING; LUMINESCENCE; RADIATIONLESS DEACTIVATION; SPIN-CROSSOVER; [CO(BPY)3]2+; [FE(BPY)3]2+; [RU(BPY)3]2+

Document Type: Research Article

Publication date: December 1, 2002

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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