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Synthetic Utility of Non-Heavy-Metal Catalysts for Hydrogen Peroxide Oxidation of Organic Compounds: Recent Advances

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Oxidation of different groups of organic compounds, with hydrogen peroxide by non-heavymetal containing low-molecular-weight compounds is reviewed. Since hydrogen peroxide is inactive toward most of the organic substrates, catalytic in situ activation of the terminal oxidant is necessary. The bases, acids, iodine and bromine, selenium compounds, flavines, triazines, amines, N-oxides, thioureas, nitriles and ketones, aluminium compounds and carbon materials are representative catalysts. They are involved in oxygen and electron transfer processes whose mechanisms are briefly discussed. Their applications in practical synthesis for the oxidative transformations of different organic compounds are indicated.
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Keywords: Catalysts; flavines; hydrogen peroxide; oxidation; selenium compounds; triazines

Document Type: Research Article

Publication date: December 1, 2016

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  • Mini-Reviews in Organic Chemistry publishes original reviews on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition, and physical organic chemistry. The emphasis will be on publishing quality papers very rapidly. Mini-reviews will be processed rapidly by taking full advantage of Internet technology for both the submission and review of manuscripts.

    The journal is essential reading to all organic chemists in both academia and industry.
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