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Bis-quinolizidine Complexes: Structure, Spectroscopic Properties and Theoretical Calculations

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Coordination compounds based on bis-quinolizidine derivatives as ligands are described from the viewpoint of their spectroscopic and structural properties. The metal ligand ability of C2 substituted sparteines and bis-quinolizidine Noxides is discussed in order to establish how far the presence of a substituent at α position to the nitrogen atom, involved in the formation of metal complexes or N-oxide function, influences the course of the complexation reaction and geometry of the complexes. The results are confronted with theoretical calculations. Potential pharmacological properties of selected complexes are also determined.
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Keywords: Bis-quinolizidine N-oxides; metal complexes; sparteine derivatives; spectroscopic properties; theoretical calculations; x-ray structure

Document Type: Research Article

Publication date: August 1, 2013

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  • Mini-Reviews in Organic Chemistry publishes original reviews on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition, and physical organic chemistry. The emphasis will be on publishing quality papers very rapidly. Mini-reviews will be processed rapidly by taking full advantage of Internet technology for both the submission and review of manuscripts.

    The journal is essential reading to all organic chemists in both academia and industry.
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