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Catalytic Aldehyde Olefinations

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Several efficient catalytic aldehyde olefination reactions reported, since the late 1980s, are described. This paper deals with the results obtained with several metals. The reaction conditions, selectivities and the yields obtained are presented. Furthermore, the mechanisms suggested by the different authors are discussed in some detail.
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Keywords: aldehyde; carbene; catalytic; olefination; transition-metal; ylide

Document Type: Review Article

Affiliations: Anorganisch-Chemisches Institut der Technischen Universitat München, Lichtenbergstrabe 4, D- 85747 Garching bei München, Germany.

Publication date: January 1, 2004

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  • Mini-Reviews in Organic Chemistry publishes original reviews on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition, and physical organic chemistry. The emphasis will be on publishing quality papers very rapidly. Mini-reviews will be processed rapidly by taking full advantage of Internet technology for both the submission and review of manuscripts.

    The journal is essential reading to all organic chemists in both academia and industry.
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