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Applications of the in situ Propargyl-Allenyl Isomerization in Organic Synthesis

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Allenes have been shown to be versatile building blocks in organic synthesis. However, the diversity of the allene chemistry offers a challenging and exquisite task for organic chemists bent on building the suitable allene substrates. A good solution might be propargyl-allenyl isomerization, which means to prepare readily available propargyl substrates. This review focuses on recent progress in the in situ propargyl-allenyl isomerization in organic synthesis, published in 1990 and later.
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Keywords: Allene; Base-promotion; Cyclization; Propargyl Ether; Propargyl-allenyl isomerization; bis-propargylic sulfides; coupling–isomerization–Claisen; cycloaddition; nitrogen; sulfur (selenium)

Document Type: Research Article

Publication date: July 1, 2012

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