Hydroxylated Dendrimer-Stabilized Gold and Silver Nanoparticles: Spontaneous Formation, Characterization, and Surface Properties
We present a general route to the facile and spontaneous synthesis of gold (Au) and silver (Ag) nanoparticles (NPs) through the use of hydroxylated poly(amidoamine) (PAMAM) dendrimers as both stabilizers and reducing agents. The formation of Au NPs can be achieved by simply mixing the generation 4 (G4) and 5 (G5) glycidol-modified PAMAM dendrimers with HAuCl4 in either methanol or water at room temperature. The size of the formed Au NPs can be varied through the change of dendrimer generations and reaction solvents. We also show that 1,2-epoxyhexane-modified G4 PAMAM dendrimers can be used as both stabilizers and reducing agents to form Au NPs, providing a useful approach to tuning the surface hydrophilicity of Au NPs. Furthermore, using the same strategy of spontaneous formation of Au NPs, Ag NPs can be readily formed through the use of glycidol hydroxyl-terminated G5 PAMAM dendrimers as both stabilizers and reducing agents. The facile synthesis of Au and Ag NPs using hydroxylated PAMAM dendrimers may offer many opportunities for their uses in a variety of applications.
No Supplementary Data
No Article Media
Document Type: Research Article
Publication date: June 1, 2010
More about this publication?
- Current Nanoscience publishes authoritative reviews and original research reports, written by experts in the field on all the most recent advances in nanoscience and nanotechnology. All aspects of the field are represented including nano- structures, synthesis, properties, assembly and devices. Applications of nanoscience in biotechnology, medicine, pharmaceuticals, physics, material science and electronics are also covered. The journal is essential to all involved in nanoscience and its applied areas.
- Editorial Board
- Information for Authors
- Subscribe to this Title
- Ingenta Connect is not responsible for the content or availability of external websites