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Effect of the Ligand Field Geometry on the Slow Magnetization Relaxation in Mononuclear Dysprosium Complexes

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Two mononuclear complexes containing a Dy(III) ion with eight- and nine-coordinate environments have been successfully synthesized and structurally characterized by single-crystal X-ray crystallography. The coordination spheres of 1 and 2 exhibit the distorted spherical capped square antiprism and square antiprism geometries. Magnetic measurements reveal that both of the complexes show typical single-molecule magnetic behavior, and only complex 2 presents a butterfly hysteresis loop. Ab initio calculations also show the difference of the magnetic anisotropy of the Dy(III) ions in 1 and 2. The relationship between the coordination geometry and the magnetic property is discussed.
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Keywords: DYSPROSIUM; MAGNETIC PROPERTIES; MOLECULAR MAGNET; SINGLE-ION MAGNET

Document Type: Research Article

Publication date: September 1, 2018

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  • Science of Advanced Materials (SAM) is an interdisciplinary peer-reviewed journal consolidating research activities in all aspects of advanced materials in the fields of science, engineering and medicine into a single and unique reference source. SAM provides the means for materials scientists, chemists, physicists, biologists, engineers, ceramicists, metallurgists, theoreticians and technocrats to publish original research articles as reviews with author's photo and short biography, full research articles and communications of important new scientific and technological findings, encompassing the fundamental and applied research in all latest aspects of advanced materials.
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