Skip to main content
padlock icon - secure page this page is secure

Self-Assembly Behaviors of a Well-Defined Amphiphilic Brush Polymer at the Air-Water Interface

Buy Article:

$106.81 + tax (Refund Policy)

Self-assembly characteristics of a well-defined brush polymer, poly(oxy(n-dodecyl-thiomethyl)ethylene) were in detail investigated at the air-water interface with surface–area isotherm, X-ray reflectivity, and infrared spectroscopy analyses. The brush polymer self-assembled at the air-water interface as a fully-extended chain via favorable lateral packing of the bristles in a fully extended conformation, forming highly ordered, oriented Langmuir monolayer. This well-ordered monolayer was produced via a five-regime structure formation with varying surface pressure. A Langmuir monolayer film with ≤1.92 nm thick was formed in the low surface pressure regime ≤18 mN/m and then converted to a highly dense, ordered monolayer with 3.65 nm thick in the high surface pressure regime ≥35 mN/m through monolayer-to-bilayer transition and bilayer-to-monolayer inversion. These Langmuir film formations and their ordering and orientation might be driven by the well-defined chemical architecture and the lateral orderings of the polymer backbones and the bristles in fully extended conformations.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
No Metrics


Document Type: Research Article

Publication date: November 1, 2014

More about this publication?
  • Science of Advanced Materials (SAM) is an interdisciplinary peer-reviewed journal consolidating research activities in all aspects of advanced materials in the fields of science, engineering and medicine into a single and unique reference source. SAM provides the means for materials scientists, chemists, physicists, biologists, engineers, ceramicists, metallurgists, theoreticians and technocrats to publish original research articles as reviews with author's photo and short biography, full research articles and communications of important new scientific and technological findings, encompassing the fundamental and applied research in all latest aspects of advanced materials.
  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Ingenta Connect is not responsible for the content or availability of external websites
  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more