Nanostructured Tin-Doped Indium Oxide for CO Sensing
Hydrothermally synthesised nanostructured tin-doped indium oxide (ITO) has been employed as a sensing material for the detection of CO gas in a mixed potential sensor. Scandia stabilized zirconia (ScSZ) has been used as a solid-state oxide ion conducting membrane for sensing different
CO concentrations from ∼100 ppm to ∼500 ppm. Monodispersed ITO particles with spherical shape have been obtained by hydrothermally treating the mixture of the coprecipitated gels with urea as an additive. Directly using urea as the mineralizer, the two coexisting morphologies such
as rodlike and spherical shapes have been obtained. The sensor coupling spherical 5 at.% tin-doped indium oxide (5ITO) electrode shows the better sensitivity than the sensors coupling both spherical 8 at.% tin-doped indium oxide (S8ITO) and 8 at.% tin-doped indium oxide (RS8ITO) containing
spherical and rod-like coexisting particle morphologies. The sensor coupling spherical 5 at.% tindoped indium oxide (5ITO) electrode also exhibits highly reproducible and stable signals to different CO concentrations.
Keywords: CO SENSOR; HYDROTHERMAL SYNTHESIS; MIXED POTENTIAL; NANOSTRUCTURED; SCANDIUM OXIDE STABILIZED ZIRCONIA; SOLID ELECTROLYTE; TIN-DOPED INDIUM OXIDE
Document Type: Research Article
Publication date: 01 October 2011
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