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Synthesis of the Ag Nanospheres, Nanodendrites and [email protected](p-diaminoazobenzene) Composites by Smart Photoisomerization of the p-Diaminoazobenzene

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In this paper, we used a simple, facile way to synthesize the new [email protected](p-diaminoazobenzene) composites, Ag nanospheres and nanodendrites. The samples were synthesized by adding the AgNO3 aqueous solution into p-diaminoazobenzene (PDAAB) solution directly, without any surfactants or other agents. Different spectroscopy analyses, such as scanning electron microscopy (SEM), X-ray diffraction (XRD), Infrared spectroscopy (IR), and Raman spectroscopy were used to clarify our results. The molar ratio and concentration of the PDAAB/AgNO3 play a sole role in the morphology and size of the samples. Upon the ultraviolet (UV) irradiation, the morphology formed by the PDAAB would be grown to flowerlike structures as the natural templates or stems due to the photoisomerization of the azobenzenze moieties, and the self-organized silver nanoparticles were able to absorb on the stem. Finally, the Ag nanodendrites were formed. Furthermore, a possible formation mechanism was discussed.
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Keywords: AG; MORPHOLOGIES; PDAAB; PHOTOISOMERIZATION; POWDERS

Document Type: Short Communication

Publication date: April 1, 2014

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  • Nanoscience and Nanotechnology Letters (NNL) is a multidisciplinary peer-reviewed journal consolidating nanoscale research activities in all disciplines of science, engineering and medicine into a single and unique reference source. NNL provides the means for scientists, engineers, medical experts and technocrats to publish original short research articles as communications/letters of important new scientific and technological findings, encompassing the fundamental and applied research in all disciplines of the physical sciences, engineering and medicine.
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