Far-Infrared Absorption by Acoustic Phonons in Titanium Dioxide Nanopowders
We report spectral features of far-infrared electromagnetic radiation absorption in anatase TiO2 nanopowders that we attribute to absorption by acoustic phonon modes of nanoparticles. The frequency of peak excess absorption above the background level corresponds to the predicted frequency of the dipolar acoustic phonon from continuum elastic theory. The intensity of the absorption cannot be accounted for in a continuum elastic dielectric description of the nanoparticle material. Quantum mechanical scale-dependent effects must be considered. The absorption cross section is estimated from a simple mechanical phenomenological model. The results are in plausible agreement with the absorption being due to a sparse layer of charge on the nanoparticle surface.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
Document Type: Research Article
Publication date: April 1, 2006
More about this publication?
- Journal of Nanoelectronics and Optoelectronics (JNO) is an international and cross-disciplinary peer reviewed journal to consolidate emerging experimental and theoretical research activities in the areas of nanoscale electronic and optoelectronic materials and devices into a single and unique reference source. JNO aims to facilitate the dissemination of interdisciplinary research results in the inter-related and converging fields of nanoelectronics and optoelectronics.
- Editorial Board
- Information for Authors
- Subscribe to this Title
- Ingenta Connect is not responsible for the content or availability of external websites