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Surfactant-Assisted Mesostructural Variation by the Molecular Structure of Frameworks

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Typical syntheses for the mesostructural design were performed with strategic deviations, being substantially powerful for changing the molecular structure of frameworks, from the synthetic conditions optimized for the preparation of lamellar and 2-d hexagonal mesostructured materials where the frameworks were constructed by aluminophosphate (AlPO) like units with and without organic groups in the molecular scale. A series of the materials such as mesostructured aluminum organophosphonate (AOP) and AlPO type ones were investigated according to the molecular structure and crystallinity of inorganic–organic hybrid and non-hybrid inorganic frameworks. Considering a uniqueness of AlPO based frameworks, a rational insight on strength of interactions between crystalline/amorphous AlPO based units and cationic surfactant molecules was surveyed as one of the most significant factors for understanding the mesostructural variation.
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Keywords: Designed Interval; Framework Crystallinity; Mesostructural Formation; Molecular Ordering; Nanoarchitectonics

Document Type: Research Article

Affiliations: Inorganic Functional Materials Research Institute, National Institute of Advanced Industrial Science and Technology (AIST) Shimoshidami, Moriyama-ku, Nagoya 463-8560, Japan

Publication date: May 1, 2020

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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