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Electrochemical Study of Bimetal Organic Frameworks with Graphene Oxide for Lithium-Sulfur Cells as Nanoarchitectonics

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We studied that hybrid material of metal organic framework, using two different metals (bimetal organic frameworks), containing graphene oxide (GO) as a sulfur immobilizing host was successfully synthesized by hydrothermal reaction. Composites were prepared using ligands of varying ratios to observe the structure properties depending on the amount of ligand used. Field emission scanning electron microscopy (FE-SEM), Fourier Transform Infra-Red Spectroscopy (FT-IR), and X-ray diffraction (XRD) were conducted to determine the morphology and micro-structure of the composite. Electrochemical properties were characterized by cyclic voltammetry (CV) and galvanostatic charge–discharge tests. Based on these study, bimetal organic frameworks showed different morphology by ligand amounts and the enhanced performance for Li–S battery cathode.
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Keywords: Electrochemistry; Graphene; Lithium-Sulfur Cells; Metal Organic Frameworks; Nanoarchitectonics

Document Type: Research Article

Affiliations: 1: Department of Chemical and Biomolecular Engineering, Pusan National University, 2, Busandaehak-ro 63 beon-gil, Geumjeong-gu, Busan 46241, South Korea 2: Department of Chemical Engineering, Korea University of Technology and Education, Chunjeolno, Byeongchun, Cheonan-si 31253, South Korea

Publication date: May 1, 2020

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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