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Controlled Synthesis of Silver Micro/Nano Leaves for Oxygen Reduction and CO2 Reduction

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In this study, three different Ag micro/nano leaves were successfully synthesized through a galvanic displacement reaction by adjusting the concentration of Ag+. The catalytic activities of the prepared Ag micro/nano leaves toward ORR showed strong dependence on their morphology. An optimal concentration of Ag+ can result in a well-defined Ag micro/nano leaves with both crystallization and surface area, which showed the best activity towards ORR in alkaline media. In addition, the prepared Ag micro/nano leaves also showed high activity towards CO2 reduction, which required a potential of −0.8 V versus RHE to selectively convert CO2 to CO with the faradaic efficiency at about 20%. Compared with the Ag plate at the same overpotential, the FE has increased by 5-fold.

Keywords: CO2 Reduction; Morphology Control; Oxygen Reduction; Silver Dendrite

Document Type: Research Article

Affiliations: 1: Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, 100190, Beijing, China 2: Zhengzhou Tobacco Research Institute of CNTC, 450001, Zhengzhou, China

Publication date: 01 August 2018

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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