Nanostructured Titania Templated by Natural Cellulose Substance: Effect of Vanadium-Doping on the Anatase-to-Rutile Phase Transformation
Vanadium-doped rutile titania nanomaterial was synthesized by calcination of titania/vanadia composite thin gel films pre-coated natural cellulose substance (e.g., ordinary filter paper) at a relatively low temperature (600 °C). A better mixture of titanium and vanadium species
is achieved during the layer-by-layer (LbL) deposition process with cellulose nanofiber as a template, leading to more vanadium dopants incorporated in the titania crystal lattices. By sufficient vanadium-doping, the phase transformation temperature from anatase to rutile phase of titania
is decreased effectively. The doping mode and existing state of vanadium in the titania nanomaterials and the effect on the anatase-to-rutile phase transformation have been studied. This strategy provides a facile and effective route to facilitate the phase transformation of various nanostructured
metal oxides templated by natural cellulose substance through doping appropriate functional metal ions in the LbL deposition process.
Keywords: Biomimetic; Ceramics; Phase Transformation; Sol–Gel Preparation; Titania
Document Type: Research Article
Affiliations: Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027, China
Publication date: 01 February 2018
- Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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