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Synthesis of Thienopyrrolodione-Based Copolymers and Their Application in Organic Thin-Film Transistors

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Two thienopyrrolodione (TPD)-based polymers, 24DTT-TPD and 24DTS-TPD, were synthesized by carrying out Stille coupling reactions. The obtained polymers were characterized by 1H NMR, FT-IR, mass analysis, UV-visible spectroscopy, cyclic voltammetry, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The deposited films were characterized by X-ray diffraction. Synthesized polymers showed good solubility in common solvents. The solution-processed organic field-effect transistors showed field-effect mobility values of 4.5×10-5 cm2/Vs for 24DTT-TPD and 2.9×10-2 cm2/Vs for 24DTS-TPD at optimal conditions.
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Keywords: Organic Transistors; Polymeric Semiconductor; Thienopyrrolodione

Document Type: Research Article

Affiliations: 1: Department of Chemistry and RINS, Gyeongsang National University, Jin-ju, 660-701, Republic of Korea 2: POSTECH Organic Electronics Laboratory, Polymer Research Institute, Department of Chemical Engineering,Pohang University of Science and Technology, Pohang, 790-784, Republic of Korea 3: Department of Materials Engineering and Convergence Technology, Gyeongsang National University, Jin-ju, 660-701, Republic of Korea 4: Department of Polymer Science and Engineering and Department of IT Convergence, Korea National University of Transportation, 50 Daehak-Ro, Chungju, 27469, Republic of Korea

Publication date: August 1, 2017

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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