An Environmentally-Conscious Approach to the Synthesis and Separation of Ultrasmall Si Nanoparticles
Silicon nanoparticles (SiNPs) are an attractive material due to their efficient emission, photostability, and biocompatibility. Given the size-dependent physiochemical and optical properties of SiNPs, the ability to generate a monodisperse population stands out as a crucial next step
for translation to the commercial and health sectors. Unfortunately, such demand is hindered on two fronts: (1) the detrimental environmental impact of manufacturing silicon wafers (a prerequisite to generate SiNPs), and (2) the difficulty in achieving a narrow size distribution of SiNPs.
Herein, we report on an efficient preparation method via used Si wafers and the size/charge-based separation of SiNPs via capillary electrophoresis (CE). We obtain blue-shifted fluorescent SiNPs with an average diameter of 3.17 nm as assessed via transmission electron microscopy and demonstrate
the use of CE to further refine and narrow the distribution of SiNPs by particle diameter and surface charge. Ultimately, we propose an economical and environmentally-friendly alternative, and envision that size-based separation of SiNPs via CE can be expanded to other fields as a standard
protocol for size characterization.
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Document Type: Research Article
Center for Biomaterials, Korea Institute of Science and Technology, Seoul, 136-120, Republic of Korea
School of Chemical Engineering, Sungkyunkwan University, Suwon, 440-746, Republic of Korea
Department of Chemical Engineering, College of Engineering, Kyung Hee University, Yongin, 446-701, Republic of Korea
Department of BioNano Technology, Hanyang University, Seoul, 133-791, Republic of Korea
July 1, 2016
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Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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