Bio-Diesel Production from Deoxygenation Reaction Over Ce0.6Zr0.4O2 Supported Transition Metal (Ni, Cu, Co, and Mo) Catalysts
Ce0.6Zr0.4O2 supported transition metal (Me =Ni, Cu, Co, and Mo) catalysts have been investigated to screen for the catalytic activity and selectivity for deoxygenation reaction of oleic acid. Me– Ce0.6Zr0.4O2 catalysts
were prepared by a co-precipitation method. Ni–Ce0.6Zr0.4O2 catalyst exhibited much higher oleic acid conversion, selectivity for C9 to C17 compounds, and oxygen removal efficiency than the others. This is mainly ascribed to the
presence of free Ni species, synergy effects between Ni and Ce0.6Zr0.4O2, and the highest BET surface area.
Keywords: Ce0.6Zr0.4O2; Deoxygenation; Ni; Synergy Effect; Transition Metal
Document Type: Research Article
Affiliations: 1: Department of Environmental Engineering, Yonsei University, 1 Yonseidae-Gil, Wonju, Gangwon, 220-710, S. Korea 2: Biomass and Waste Energy Laboratory, Korea Institute of Energy Research (KIER), Daejeon, 305-343, S. Korea 3: Petroleum and Gas Research Center, Korea Institute of Energy Research (KIER), Daejeon, 305-343, S. Korea 4: School of Applied Chemical Engineering, Chonnam National University, 77 Yongbong-ro, Buk-Gu, Gwangju, 500-757, S. Korea
Publication date: 01 May 2016
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