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Bio-Diesel Production from Deoxygenation Reaction Over Ce0.6Zr0.4O2 Supported Transition Metal (Ni, Cu, Co, and Mo) Catalysts

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Ce0.6Zr0.4O2 supported transition metal (Me =Ni, Cu, Co, and Mo) catalysts have been investigated to screen for the catalytic activity and selectivity for deoxygenation reaction of oleic acid. Me– Ce0.6Zr0.4O2 catalysts were prepared by a co-precipitation method. Ni–Ce0.6Zr0.4O2 catalyst exhibited much higher oleic acid conversion, selectivity for C9 to C17 compounds, and oxygen removal efficiency than the others. This is mainly ascribed to the presence of free Ni species, synergy effects between Ni and Ce0.6Zr0.4O2, and the highest BET surface area.

Keywords: Ce0.6Zr0.4O2; Deoxygenation; Ni; Synergy Effect; Transition Metal

Document Type: Research Article

Affiliations: 1: Department of Environmental Engineering, Yonsei University, 1 Yonseidae-Gil, Wonju, Gangwon, 220-710, S. Korea 2: Biomass and Waste Energy Laboratory, Korea Institute of Energy Research (KIER), Daejeon, 305-343, S. Korea 3: Petroleum and Gas Research Center, Korea Institute of Energy Research (KIER), Daejeon, 305-343, S. Korea 4: School of Applied Chemical Engineering, Chonnam National University, 77 Yongbong-ro, Buk-Gu, Gwangju, 500-757, S. Korea

Publication date: 01 May 2016

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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