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Construction of Long-Wavelength-Light Photocurrent Generation System Based on Self-Assembled Monolayer of Cobaltadithiolene [60]Fullerene Complex

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[60]Fullerene pentaester and pentaacid derivatives bearing cobaltadithiolene dyes were successfully synthesized under mild reaction conditions. Self-assembled monolayers (SAMs) of the pentaacid derivative were prepared by an immersion method and the photocurrent generation properties of the SAMs were measured. Due to the introduction of the light-absorbing cobaltadithiolene moiety, the range of available wavelengths for photoelectric conversion was extended to λ = 700 nm, which is longer than that of conventional penta(organo)[60]fullerene carboxylic acids.
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Document Type: Research Article

Publication date: August 1, 2012

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  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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