Construction of Long-Wavelength-Light Photocurrent Generation System Based on Self-Assembled Monolayer of Cobaltadithiolene Fullerene Complex
Fullerene pentaester and pentaacid derivatives bearing cobaltadithiolene dyes were successfully synthesized under mild reaction conditions. Self-assembled monolayers (SAMs) of the pentaacid derivative were prepared by an immersion method and the photocurrent generation properties of the SAMs were measured. Due to the introduction of the light-absorbing cobaltadithiolene moiety, the range of available wavelengths for photoelectric conversion was extended to λ = 700 nm, which is longer than that of conventional penta(organo)fullerene carboxylic acids.
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Document Type: Research Article
Publication date: August 1, 2012
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