Skip to main content
padlock icon - secure page this page is secure

Electronic Coupling in Diiron Complexes with the Butadienediyl-Bridged Chain

Buy Article:

$106.23 + tax (Refund Policy)

The butadienediyl-bridged complexes [η 5-C5Me5]Fe(CO)(PPh3)]2(μ-CH=CH–CH=CH) have been prepared and characterized by cyclic voltammetry, NMR, and X-ray crystallography. Compound 3 diastereomers showed two reversible one-electron oxidations at −0.053∼–0.056 V and −0.02∼0.03 V, respectively. The comproportionation constant, Kc, was calculated from these measurements. Kc values are very high, 1.0∼3.0 ×109. These values are consistent with the Robin-Day Mixed-Valence Class III.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
No Metrics


Document Type: Research Article

Publication date: February 1, 2011

More about this publication?
  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Terms & Conditions
  • Ingenta Connect is not responsible for the content or availability of external websites
  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more