Skip to main content
padlock icon - secure page this page is secure

Substituent Effect on Color Tuning of Red Light Emission in Photoluminescence and Electroluminescence of Red Fluorophore

Buy Article:

$106.51 + tax (Refund Policy)

Typical small red light-emitting molecules for organic light emitting diodes (OLEDs) were highly susceptible to fluorescence concentration quenching in solid state. Red fluorophores, (2Z, 2′Z)-3, 3′-[4,4″-bis(dimethylamino)-1,1′:4′,1″-terphenyl-2′,5′-diyl]bis(2-phenylacrylonitrile) (ABCV-P), (2E, 2′E)-3,3′-[4,4″-bis(dimethylamino)-1,1′:4′,1″-terphenyl-2′,5′-diyl]bis[2-(2-thienyl)acrylonitrile] (ABCV-Th) and (2Z, 2′Z)-3,3′-[4,4″-bis(dimethylamino)-1,1′:4′,1″-terphenyl-2′,5′-diyl]bis[2-(2-naphthyl)acrylonitrile] (ABCV-Np), capable of preventing fluorescence concentration quenching were designed and synthesized. These compounds have intramolecular charge transfer (ICT) properties which were estimated by measurement of UV-Visible absorption and photoluminescence (PL) emission spectra with variation of solvent polarity (n-Hexane/Chloroform = 99/1, 1/1; Chloroform; Methylene chloride). The magnitude of ICT for ABCV-Th was measured to be the largest and that for ABCV-Np was slightly larger compared to that for ABCV-P. The magnitude of ICT resulted in a shift of peak wavelength of PL emission. Therefore, this result well supported substituent effect on the color change of PL emission. The peak wavelengths of photoluminescence for ABCV-P, ABCV-Np and ABCV-Th were observed to be 607.5, 611.5 and 617.5 nm, respectively, and those of EL spectra were measured to be 612.5, 619.5, 621.0 nm, respectively. The emission maxima of PL and EL spectra for these red fluorescent compounds were well correlated with substituent effect on ICT for them.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
No Metrics


Document Type: Research Article

Publication date: October 1, 2010

More about this publication?
  • Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Terms & Conditions
  • Ingenta Connect is not responsible for the content or availability of external websites
  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more