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Kinematical Studies of Thermal Crystallization in Glassy Se78–x Te20Sn2Bi x (0 ≤ x ≤ 6) Alloys

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In this study, we report the results of calorimetric measurements on the samples of glassy Se78–x Te20Sn2Bi x (0 ≤ x ≤ 6) alloys. For non-isothermal study of crystallization kinetics, DSC scans have been used. Peak crystallization temperature (Tc ), crystallization enthalpy (ΔHc ), entropy change during the crystallization (ΔS) are determined using these DSC thermo-grams. Activation energy of crystallization (Ec ) has been calculated using Kissinger, Matusita-Sakka, and Augis-Bennett methods. Rate constants K of crystallization, its peak value Kp and frequency factor K 0 are also obtained. The chemical bond approach is used to explain results.
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Keywords: CHALCOGENIDE GLASSES; CRYSTALLIZATION KINETICS; DIFFERENTIAL SCANNING CALORIMETRY

Document Type: Research Article

Publication date: September 1, 2013

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  • Journal of Advanced Physics is an interdisciplinary peer-reviewed journal consolidating research activities in all experimental and theoretical aspects of advanced physics. The journal aims in publishing articles of novel and frontier physics that merit the attention and interest of the whole physics community. JAP publishes review articles, full research articles, short communications of important new scientific and technological findings in all latest research aspects of physics.
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