Structural Aspects, Biological and Nonlinear Optical Response of New N,N–Di(2-tolyl)Formamidinium Tosylate
N,N –Di(2-tolyl)formamidine (1) was protonated with the aim to explore the structural and solid state properties of the resulting salt. Compound 1 upon protonation with p-toluene sulphonic acid hydrate afforded N,N–Di(2-tolyl)formamidinium tosylate, [1H]+OTs– in 90% yield. Compound 1 and [1H]+ OTs– were fully characterized by analytical, IR and NMR (1H & 13C) spectroscopic data. The composition of [1H]+OTs– was further confirmed by single crystal X-ray diffraction data. The tosylate salt [1H]+OTs– crystallized in P21/n space group and exhibited moderate N–H···O and C–H···O hydrogen bonding pattern in the crystal lattice. The thermal stability of [1H]+OTs– was evaluated by TGA technique. Both the molecules were found to be moderately active against bacterial strains Staphylococcus aureus, Listeria monocytogenes, Bacillus subtilis, Enterococcus faecalis, Klebsiella pneumoniae, Escherichia coli and Pseudomonas aeruginosa. Further, [1H]+ OTs– was evaluated for second harmonic generation response by Kurtz-Perry powder technique.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
Document Type: Research Article
Publication date: June 1, 2013
More about this publication?
- Advanced Chemistry Letters is an international multidisciplinary peer-reviewed journal covering all fundamental and applied research areas of chemical sciences including organic chemistry, inorganic chemistry, synthetic chemistry, medicinal chemistry, analytical chemistry, organometallic chemistry, nuclear chemistry, electrochemistry, atmospheric chemistry, environmental chemistry, materials chemistry, materials science, supramolecular chemistry, physical chemistry, polymer chemistry, bioinorganic chemistry, physical organic chemistry, surface chemistry, biochemistry, molecular biology, chemical biology, food chemistry, natural product chemistry, neurochemistry, pharmacology, photochemistry, photobiology, toxicology, nanoscience, nanotechnology, agrochemistry, green chemistry, marine chemistry, geochemistry, petrochemistry, radiochemistry, astrochemistry, molecular physics, chemical engineering, quantum chemistry, and theoretical and computational chemistry.
- Editorial Board
- Information for Authors
- Subscribe to this Title
- Aims and Scope
- Ingenta Connect is not responsible for the content or availability of external websites