Electrochemical CO2 Reduction on a Copper Wire Electrode in Tetraethylammonium Perchlorate Methanol at Extremely Low Temperature
The electrochemical reduction of CO2 in tetraethylammonium perchlorate methanol electrolyte was investigated with a copper wire electrode at an extremely low temperature (-30 C). The main products from CO2 by the electrochemical reduction were methane, ethylene, carbon monoxide, and formic acid. Under the optimum experimental conditions, 28.1% faradaic efficiency methane, 7.2% ethylene, 67.8% carbon monoxide, and 23.2% formic acid were produced from CO2 by the electrochemical reduction. The maximum partial current densities for CO2 reduction and hydrocarbons were 4.5 and 1.6 mA cm-2 at 4.0 V vs SCE, respectively. At -30 C, the efficiency of hydrogen formation, being a competitive reaction against CO2 reduction, was suppressed to less than 10.1%.
Keywords: CARBON DIOXIDE; COPPER WIRE ELECTRODE; ELECTROCHEMICAL REDUCTIONS; TETRAETHYLAMMONIUM PERCHLORATE METHANOL ELECTROLYTE
Document Type: Research Article
Publication date: 01 August 1999
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