Chiral N-Acetyl Selone-Promoted Aldol Reactions
The chiral oxazolidineselone functionality was found to be an excellent partner in the stereospecific acetate aldol reaction with aldehydes via the titanium enolates. Good stereocontrol was obtained as determined by NMR spectroscopy. The oxazolidineselone also provided a straightforward way to establish the stereopurity of the coupling reaction through 77Se NMR spectroscopy.
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77Se NMR spectroscopy;
Document Type: Research Article
National Stable Isotope Resource, Bioenergy and Environmental Sciences Group (B8), Los Alamos National Laboratory, Los Alamos, New Mexico, USA
Advanced Measurement Science Group (B9), Bioscience Division, Los Alamos National Laboratory, Los Alamos, New Mexico, USA
NMT Division, Los Alamos National Laboratory, Bioscience Division, Los Alamos, New Mexico, USA
Publication date: 01 January 2009