Skip to main content
padlock icon - secure page this page is secure

Amine-tetrachloromethane charge transfer complexes: a structural and computational study

Buy Article:

$60.00 + tax (Refund Policy)

Amine-tetrachloromethane charge-transfer complexes have recently been shown to be useful intermediates in transition-metal free solar light-assisted organic synthetic chemistry. Of particular promise is the complex of 1,4-diazabicyclo[2.2.2]octane (DABCO) which may serve as a starting point for several potential reactions involving oxidation of organic compounds. Here we disclose the crystal structure of the [DABCO•••CCl4] complex, and computational studies of two possible complex structures in their ground state, as well as in their first singlet and first triplet excited states.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
No Metrics

Keywords: Amines; charge-transfer complexes; light-induced processes; organic synthesis; tetrachloromethane

Document Type: Research Article

Affiliations: 1: Schulich Faculty of Chemistry, Technion – Israel Institute of Technology, Haifa, Israel; 2: Department of Chemical Sciences, Ariel University, Ariel, Israel

Publication date: July 3, 2018

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more