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From mononuclear to polynuclear: copper and zinc complexes obtained from polypyridylamine ligands related to tris(2-pyridylmethyl)-amine (tmpa)

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Copper(I)/(II) complexes and a zinc compound with polypyridylamine ligands (related to the tripodal ligand tris(2-pyridylmethyl)amine, tmpa) were synthesized. Crystallographic characterization was possible for most of the complexes obtained. The different structures of the complexes allowed some insight into the basic understanding of the design of coordination polymers. Depending on ligand, solvent or anion, either mononuclear, dinuclear or polynuclear complexes were obtained.
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Keywords: Copper; coordination polymer; dinuclear; polynuclear; zinc

Document Type: Research Article

Affiliations: 1: Institut für Anorganische und Analytische Chemie, Justus-Liebig-Universität Gießen, Gießen, Germany; 2: School of Pharmacy, Tianjin Medical University, Tianjin, P. R. China; 3: Fachbereich Chemie, Technische Universität Kaiserslautern, Kaiserslautern, Germany; 4: European Commission, DG Joint Research Centre, Directorate G – Nuclear Safety and Security, G.I.5 – Advanced Nuclear Knowledge, Karlsruhe, Germany

Publication date: July 3, 2018

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