Synthesis and characterization of an amethyrin-uranyl complex displaying aromatic character
The reaction between amethyrin and non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2) under anaerobic conditions affords a bench-stable uranyl complex. UV–vis spectroscopy, cyclic voltammetry, as well as proton NMR spectroscopic analyses
provide support for the conclusion that all six pyrrole subunits participate in coordination of the uranyl dication and that, upon complexation, the amethyrin-core undergoes a 2-electron oxidation to yield a formal 22 π-electron aromatic species.
Keywords: Amethyrin; actinide; expanded porphyrin; hexaphyrin; uranyl
Document Type: Research Article
Affiliations: Department of Chemistry, The University of Texas at Austin, Austin, TX, USA
Publication date: 03 July 2018
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