Skip to main content
padlock icon - secure page this page is secure

Reactions of carbonate radical anion with amino-carboxylate complexes of manganese(II) and iron(III)

Buy Article:

$60.00 + tax (Refund Policy)

The reaction kinetics of eight amino-carboxylate complexes of Fe(III) and Mn(II) with carbonate radical anion were studied using the pulse radiolysis method and UV-vis spectroscopy. Difference spectra revealed the formation of Fe(IV) and Mn(III) after reaction with CO3 •−. Spectral measurements revealed the first step to be the coordination of carbonate to the metal center. All of these led to the conclusion that the role of coordinated carbonate is essential to the electron transfer process by carbonate radical anion.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
No Metrics

Keywords: CO3•−; amino-carboxylate; iron(III); manganese(II); pulse radiolysis

Document Type: Research Article

Affiliations: 1: Chemistry Department, Nuclear Research Centre Negev, Beer-Sheva, Israel; 2: Chemistry Department, Ben-Gurion University of the Negev, Beer-Sheva, Israel;

Publication date: July 3, 2018

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more