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Nitric oxide release from a photoactive water-soluble ruthenium nitrosyl. Biological effects

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This research presents the synthesis and characterization of the photochemical nitric oxide (NO) precursor Ru(salenCO2H)(NO)Cl (1, salenCO2H = N,N’-ethylenebis(3,3’-bis-carboxylsalicylideneiminato). This water-soluble ruthenium nitrosyl releases NO upon photolysis with a quantum yield that is pH dependent owing to the nitrosyl to nitrite conversion of that axial ligand at higher pH. Also described are the water, oxygen, and thermal stability of 1 and the cytotoxicity and the vascular relaxivity properties of 1 in the dark and under photolysis.
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Keywords: Ruthenium nitrosyl; cell viability; myography; nitric oxide; photochemical release

Document Type: Research Article

Affiliations: 1: Department of Chemistry and Biochemistry, University of California, Santa Barbara, USA 2: Faculdade de Ciências Farmacêuticas de Ribeirão Preto, Universidade de São Paulo, Ribeirão Preto, Brazil

Publication date: July 3, 2018

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