Skip to main content
padlock icon - secure page this page is secure

The rigid isomeric 5-(x-pyridyl)-1H-tetrazole ligands-directed various isopolymolybdate-based compounds: assembly, structures, and properties

Buy Article:

$63.00 + tax (Refund Policy)

Two new isopolymolybdate-based metal–organic complexes, [Cu2(2-ptz)2(Mo4O14)0.5] (1) and [Cu3(OH)2(3-ptz)4(γ-H4Mo8O26)(H2O)4]·10H2O (2) (2-ptzH = 5-(2-pyridyl)-1H-tetrazole, 3-ptzH = 5-(3-pyridyl)-1H-tetrazole), constructed from isomeric ligands with different N-donor sites were synthesized under hydrothermal conditions. In 1, each [Mo4O14]4− cluster connected with six neighboring [Mo4O14]4− clusters through six binuclear [Cu2(2-ptz)2]2+ subunits to yield a 2-D layer. In 2, bidentate inorganic [Mo8O26]4− anions link the trinuclear [Cu3(OH)2(3-ptz)4] clusters to construct a 1-D chain. Adjacent chains connect through Mo–N bonds between the [Mo8O26]4− anions and pyridyl groups from the trinuclear clusters to form a 2-D layer. The effect of the N-donor sites of the rigid isomeric ligands on the structures of 1 and 2 was discussed. The electrochemical properties and photocatalytic activities of 1 and 2 have also been studied.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
No Metrics

Keywords: Polyoxometalate; electrochemical behavior; metal–organic complex; photocatalytic property

Document Type: Research Article

Affiliations: Department of Chemistry, Bohai University, Jinzhou, P.R. China

Publication date: January 2, 2016

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more