A series of octahedral manganese(II) complexes involving xanthates and N-donor ligands, [Mn(S2COiBu)2(phen)] (1), [Mn(S2COiBu)2(2,2′-bpy)] (2), [Mn(S2CONPr)2(phen)] (3),
[Mn(S2CONPr)2(2,2′-bpy)] (4), [Mn(S2COMe)2(2,2′-bpy)] (5), [Mn(S2CONPr)2(4,4′-bpy)]n, and [Mn2(S2CONPr)4(4,4′-bpy)3]
(6) (phen = 1,10-phenanthroline, bpy = bipyridine) was prepared. Complexes were characterized by elemental analysis, FTIR spectroscopy, TG/DSC analysis, and single-crystal X-ray diffraction. The structures are built of monomeric molecules of the complexes, except
for 6 with the 4,4′-bipyridine ligand, which contains a binuclear complex and 1D polymeric zigzag chain in one crystal.
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Document Type: Research Article
Faculty of Science, Department of Chemistry, Masaryk University, Brno, Czech Republic
Faculty of Science, Department of Inorganic Chemistry, Palacký University, Olomouc, Czech Republic
December 2, 2015