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2-Benzoimidazol-8-alkylquinolinylnickel(II) complexes as efficient catalysts for ethylene oligomerization and vinyl polymerization of norbornene

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A series of nickel complexes LNiCl2 (C1C16), where L represents 2-benzoimidazol-8-alkylquinoline and its derivatives, were prepared as potential catalysts for the oligomerization of ethylene. The molecular structure of a representative complex C2┬ĚCH3CH2OH was determined by single-crystal X-ray diffraction. Upon treatment with diethylaluminium chloride (Et2AlCl), all nickel complex pre-catalysts exhibited good activities in the oligomerization of ethylene. Furthermore, in the presence of methylaluminoxane (MAO), the nickel pre-catalysts were suitable for vinyl polymerization of norbornene.
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Keywords: 2-Benzoimidazol-8-alkylquinoline; Ethylene oligomerization; Nickel complex; Norbornene polymerization

Document Type: Research Article

Affiliations: 1: School of Materials and Metallurgy, Northeastern University, Shenyang, PR China 2: Hebei Provincal Laboratory for Dielectric and Electrolyte Materials, Northeastern University at Qinhuangdao, Qinhuangdao, PR China

Publication date: November 2, 2015

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