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Polyoxometalate tri-supported transition metal complexes containing mixed-valent transition metal ions

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Three compounds, [AsMo8V6O42][Cu(2,2-bpy)2]2[Cu(2,2-bpy)]·4H2O (1), [PMo8V6O42][Cu(2,2-bpy)2]2[Cu(2,2-bpy)]·3H2O (2) and [PMo8V6O42][Cu(2,2-bpy)2]2[Cu(2,2-bpy)]·3.5H2O (3), have been synthesized under hydrothermal conditions and characterized by IR, UV–vis, XRD, TG, elemental analysis, and X-ray diffraction analysis. Single-crystal X-ray structure analysis reveals that 1 and 2 are isostructural and isomorphous, whereas 2 and 3 are polymorphs. Polymorphs of 1 have not been synthesized yet. The mixed-valent transition metal ion in 1–3 has been further confirmed by TG analyses. Catalytic properties of 1 and 2 have also been studied.
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Keywords: Hydrogen bonds; Hydrothermal synthesis; Keggin; Polyoxometalates; Supported

Document Type: Research Article

Affiliations: 1: State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Department of Chemistry, College of Chemistry, Jilin University, Changchun, China 2: Department of Chemistry, Zhoukou Normal University, Zhoukou, China

Publication date: November 2, 2015

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