[Ni(bpy)(ox)]: a candidate in the class of Haldane gap systems (bpy = 2,2-bipyridine, ox = oxalate)
[Ni(bpy)(ox)] (bpy = 2,2-bipyridine; ox = oxalate) was solvothermally prepared in the microcrystalline form and identified by chemical analyses and IR spectroscopy. X-ray powder diffractometry indicates its isostructural character with
analogous complexes [M(bpy)(ox)], and thus, its chain-like crystal structure formed of {Ni(bpy)} building units linked by bridging oxalate anions coordinated in a bis(chelate) fashion. The temperature dependence of the magnetic susceptibility and the field dependence of
the magnetization reveal that the studied compound belongs to the class of systems with a Haldane gap. The estimated magnitude of the gap E
g ≈ 13.4 cm−1 is comparable with those found in archetypal Haldane gap systems.
Keywords: 2,2-Bipyridine; Chain structure; Excitation spectrum; Haldane gap; Nickel; Oxalate; Quantum spin chain; Rietveld method
Document Type: Research Article
Affiliations: 1: Department of Inorganic Chemistry, Institute of Chemistry, Faculty of Sciences, P.J. Šafárik University in Košice, Košice, Slovakia 2: Departamento de Química Inorgánica, Instituto de Sintesis Química y Catálisis Homogénea (ISQCH), CSIC-University of Zaragoza, Zaragoza, Spain 3: Slovak Academy of Sciences, Institute of Experimental Physics, Košice, Slovakia 4: Institute of Physics, Faculty of Sciences, P.J. Šafárik University in Košice, Košice, Slovakia
Publication date: 18 August 2015
- Access Key
- Free content
- Partial Free content
- New content
- Open access content
- Partial Open access content
- Subscribed content
- Partial Subscribed content
- Free trial content