Skip to main content
Home / Journal of Coordination Chemistry, Volume 67, Number 17

In situ assembly of a host–guest linked, mixed valence copper(II)–copper(I) coordination polymer [Cu(1,2-en)2(μ3-I)2Cu2(μ2-I)2]n via partial reduction of copper(II) under ambient conditions

Buy Article:

$71.00 + tax (Refund Policy)

Authors: Jana, Subrata 1 ; Harms, Klaus 2 ; Chattopadhyay, Shouvik 1 ; 

Source: Journal of Coordination Chemistry, Volume 67, Number 17, 2 September 2014, pp. 2954-2966(13)

Publisher: Taylor and Francis Ltd

DOI: https://doi.org/10.1080/00958972.2014.952633

A 2-D coordination polymer, [Cu(1,2-en)2(μ3-I)2Cu2(μ2-I)2]n (1), was formed at room temperature by In situ insertion of [Cu(1,2-en)2]2+ guests into 1-D chains of a [Cu2I4]2− host [1,2-en = 1,2-diaminoethane]. The structure of the complex was confirmed by single-crystal X-ray diffraction study. The shortest copper(I)–copper(I) distance within the complex is 2.89 Å.

Keywords: Coordination polymer; Copper(I); Copper(II); Crystal structure; μ3-I

Document Type: Research Article

Affiliations: 1: Department of Chemistry, Inorganic Section, Jadavpur University, Kolkata, India 2: Fachbereich Chemie, Philipps-Universität Marburg, Marburg, Germany

Publication date: 02 September 2014

Share Content

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content