In-situ preparation of macrocyclic complexes of dioxomolybdenum(VI) involving a heterocyclic precursor
Dioxomolybdenum(VI) complexes [MoO2(mac)](acac)2 (where mac = tetraazamacrocyclic ligands derived from condensation of thenil with 1,2-diaminobenzene or 2,3-diaminopyridine and their reaction with -diketones) have been prepared using dioxometal ion as kinetic template. Tentative structures of the complexes have been proposed on the basis of elemental analysis, infrared, and electronic data. All the dioxomolybdenum(VI) complexes are six-coordinate octahedral ones.
Keywords: Dioxomolybdenum(VI); Kinetic template; Macrocyclic complexes
Document Type: Research Article
Affiliations: 1: Department of Chemistry, D.A-V. College, Kanpur 200801, Uttar Pradesh, India 2: Department of Chemistry, North Eastern Regional Institute of Science and Technology (NERIST), Nirjuli, Arunachal Pradesh, India 3: Department of Chemistry, M.G.P.G. College, Gorakhpur, Uttar Pradesh, India 4: Department of Chemistry, Rajendra College, Chapra, Bihar, India
Publication date: 01 January 2011
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